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42
Subjective

Give the structure 'A' in the following reaction.

Explanation

Complete conversion can be shown as

43
Subjective

What is Hinsberg reagent?

Explanation

Benzene sulphonyl chloride $\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{SO}_2 \mathrm{Cl}\right)$ is known as Hinsberg reagent. It is used to distinguish between primary, secondary and tertiary amine.

44
Subjective

Why is benzene diazonium chloride not stored and is used immediately after its preparation?

Explanation

Benzene diazonium chloride are highly unstable and stable for a very short time span in solution at low temperature. Due to its instability, it is used immediately after its preparation.

45
Subjective

Why does acylation of $-\mathrm{NH}_2$ group of aniline reduces its activating effect?

Explanation

Acylation of $-\mathrm{NH}_2$ group of aniline reduces its activity due to resonance of lone pair of nitrogen towards the carbonyl group hence $0-, p^{-}$directive influence of amino group get disturbed.

46
Subjective

Explain why $\mathrm{MeNH}_2$ is stronger base than MeOH ?

Explanation

Basicity of $\mathrm{MeNH}_2$ and MeOH can be explained on the basis of electronegativity of N and O atom. $\mathrm{MeNH}_2$ is stronger base than MeOH because of low electronegativity value of N , it is easy for nitrogen to loose its lone pair readily than compared to MeOH .