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63
MCQ (Single Correct Answer)

Match the items of Columns I and II and mark the correct option.

Column I Column II
A. Its partial hydrolysis does not change oxidation state of central atom. 1. He
B. It is used in modern diving apparatus. 2. XeF$_6$
C. It is used to provide inert atmosphere for filling electrical bulbs. 3. XeF$_4$
D. Its central atom is in $sp^3 d^2$ hybridisation. 4. Ar

A
A - 1, B - 4, C - 2, D - 3
B
A - 1, B - 2, C - 3, D - 4
C
A - 2, B - 1, C - 4, D - 3
D
A - 1, B - 3, C - 2, D - 4
64
MCQ (Single Correct Answer)

Assertion (A) $\mathrm{N}_2$ is less reactive than $\mathrm{P}_4$.

Reason (R) Nitrogen has more electron gain enthalpy than phosphorus.

A
Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.
B
Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.
C
Assertion is correct, but Reason is wrong statement.
D
Assertion is wrong but Reason is correct statement.
E
Both Assertion and Reason are wrong statements.
65
MCQ (Single Correct Answer)

Assertion (A) $\mathrm{HNO}_3$ makes iron passive.

Reason (R) $\mathrm{HNO}_3$ forms a protective layer of ferric nitrate on the surface of iron.

A
Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.
B
Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.
C
Assertion is correct, but Reason is wrong statement.
D
Assertion is wrong but Reason is correct statement.
E
Both Assertion and Reason are wrong statements.
66
MCQ (Single Correct Answer)

Assertion (A) HI cannot be prepared by the reaction of KI with concentrated $\mathrm{H}_2 \mathrm{SO}_4$.

Reason $(\mathrm{R}) \mathrm{HI}$ has lowest $\mathrm{H}-\mathrm{X}$ bond strength among halogen acids.

A
Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.
B
Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.
C
Assertion is correct, but Reason is wrong statement.
D
Assertion is wrong but Reason is correct statement.
E
Both Assertion and Reason are wrong statements.
67
MCQ (Single Correct Answer)

Assertion (A) Both rhombic and monoclinic sulphur exist as $S_8$ but oxygen exists as $\mathrm{O}_2$.

Reason (R) 0xygen forms $p \pi$ - $p \pi$ multiple bond due to small size and small bond length but $p \pi-p \pi$ bonding is not possible in sulphur.

A
Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.
B
Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.
C
Assertion is correct, but Reason is wrong statement.
D
Assertion is wrong but Reason is correct statement.
E
Both Assertion and Reason are wrong statements.