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61
Subjective

How does a delta form at the meeting place of sea and river water?

Explanation

Formation of delta at the meeting place of sea and river water is due to coagulation. River water (colloid of sea water + clay) has many dissolved electrolytes. The place where river meets sea is the site for coagulation. Deposition of coagulated clay results in delta formation.

62
Subjective

Give an example where physisorption changes to chemisorption with rise in temperature. Explain the reason for change.

Explanation

Adsorption of $\mathrm{H}_2$ on finely divided nickel (physisorption) involves weak van der Waals' forces. When temperature is increased, hydrogen molecules dissociate into hydrogen atoms, form chemical bonds with the metal atoms at the surface (chemisorption).

63
Subjective

Why is desorption important for a substance to act as good catalyst?

Explanation

Desorption is important for a substance to act as a good catalyst so that after the reaction, the products formed on the surface separate out (desorbed) to create free surface again for other reactant molecules to approach the surface and react.

If desorption does not occur then other reactants are left with no space on the catalysts surface for adsorption and reaction will stop.

64
Subjective

What is the role of diffusion in heterogeneous catalyst?

Explanation

Diffusion of gas molecules occur at the surface of catalyst (solid) followed by adsorption. In the same way, the product formed diffuse from the surface of the catalyst leaving the surface free for more reactant molecules to get adsorbed and undergo reaction.

65
Subjective

How does a solid catalyst enhance the rate of combination of gaseous molecules?

Explanation

When gaseous molecules come in contact with the surface of a solid catalyst, a weak chemical bond is formed between the surface (catalyst) molecules and reactant (gas) molecules. Thus, concentration of reactant molecules increases at the surface.

The rate of reaction increases by adsorption of different molecules side by side facilitating the chemical reaction. Adsorption, being exothermic also help in increasing the rate of reaction (chemisorption increases with rise in temperature).