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20
MCQ (Single Correct Answer)

We have three aqueous solutions of NaCl labelled as ' A ', ' B ' and ' C ' with concentrations $0.1 \mathrm{M}, 0.01 \mathrm{M}$ and 0.001 M , respectively. The value of van't Hoff factor for these solutions will be in the order .......... .

A
$i_A< i_B< i_C$
B
$i_A>i_B>i_C$
C
$i_A=i_B=i_C$
D
$i_A< i_B> i_C$
21
MCQ (Single Correct Answer)

On the basis of information given below mark the correct option. Information

(i) In bromoethane and chloroethane mixture intermolecular interactions of $\mathrm{A}-\mathrm{A}$ and $\mathrm{B}-\mathrm{B}$ type are nearly same as $\mathrm{A}-\mathrm{B}$ type interactions.

(ii) In ethanol and acetone mixture $\mathrm{A}-\mathrm{A}$ or $\mathrm{B}-\mathrm{B}$ type intermolecular interactions are stronger than $A-B$ type interactions.

(iii) In chloroform and acetone mixture $\mathrm{A}-\mathrm{A}$ or $\mathrm{B}-\mathrm{B}$ type intermolecular interactions are weaker than $A-B$ type interactions.

A
Solution (ii) and (iii) will follow Raoult's law
B
Solution (i) will follow Raoult's law
C
Solution (ii) will show negative deviation from Raoult's law
D
Solution (iii) will show positive deviation from Raoult's law
22
MCQ (Single Correct Answer)

Two beakers of capacity 500 mL were taken. One of these beakers, labelled as " $A$ ", was filled with 400 mL water whereas the beaker labelled " $B^{\prime}$ was filled with 400 mL of 2 M solution of NaCl . At the same temperature both the beakers were placed in closed containers of same material and same capacity as shown in figure.

At a given temperature, which of the following statement is correct about the vapour pressure of pure water and that of NaCl solution?

A
Vapour pressure in container $(A)$ is more than that in container $(B)$
B
Vapour pressure in container $(A)$ is less than that in container $(B)$
C
Vapour pressure is equal in both the containers
D
Vapour pressure in container $(B)$ is twice the vapour pressure in container ( $A$ )
23
MCQ (Single Correct Answer)

If two liquids $A$ and $B$ form minimum boiling azeotrope at some specific composition then

A
$A-B$ interactions are stronger than those between $A-A$ or $B-B$
B
vapour pressure of solution increases because more number of molecules of liquids $A$ and $B$ can escape from the solution
C
vapour pressure of solution decreases because less number of molecules of only one of the liquids escape from the solution
D
$A-B$ interactions are weaker than those between $A-A$ or $B-B$
24
MCQ (Single Correct Answer)

4 L of 0.02 M aqueous solution of NaCl was diluted by adding 1 L of water. The molality of the resultant solution is ........... .

A
0.004
B
0.008
C
0.012
D
0.016