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8
MCQ (Single Correct Answer)

The CFSE for octahedral $\left[\mathrm{CoCl}_6\right]^{4-}$ is $18,000 \mathrm{~cm}^{-1}$. The CFSE for tetrahedral $\left[\mathrm{CoCl}_4\right]^{2-}$ will be

A
$18,000 \mathrm{~cm}^{-1}$
B
$16,000 \mathrm{~cm}^{-1}$
C
$8,000 \mathrm{~cm}^{-1}$
D
$20,000 \mathrm{~cm}^{-1}$
9
MCQ (Single Correct Answer)

Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type $\left[\mathrm{Pd}\left(\mathrm{C}_6 \mathrm{H}_5\right)_2(\mathrm{SCN})_2\right]$ and $\left[\mathrm{Pd}\left(\mathrm{C}_6 \mathrm{H}_5\right)_2(\mathrm{NCS})_2\right]$ are

A
linkage isomers
B
coordination isomers
C
ionisation isomers
D
geometrical isomers
10
MCQ (Single Correct Answer)

The compounds $\left[\mathrm{Co}\left(\mathrm{SO}_4\right)\left(\mathrm{NH}_3\right)_5\right] \mathrm{Br}$ and $\left[\mathrm{Co}\left(\mathrm{SO}_4\right)\left(\mathrm{NH}_3\right)_5\right] \mathrm{Cl}$ represent

A
linkage isomerism
B
ionisation isomerism
C
coordination isomerism
D
no isomerism
11
MCQ (Single Correct Answer)

A chelating agent has two or more than two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent?

A
Thiosulphato
B
Oxalato
C
Glycinato
D
Ethane-1, 2-diamine
12
MCQ (Single Correct Answer)

Which of the following species is not expected to be a ligand?

A
NO
B
$\mathrm{NH}_4^{+}$
C
$\mathrm{NH}_2 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2$
D
CO