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45
MCQ (Single Correct Answer)

Assertion (A) A solution containing a mixture of acetic acid and sodium acetate maintains a constant value of pH on addition of small amounts of acid or alkali.

Reason (R) A solution containing a mixture of acetic acid and sodium acetate acts as buffer solution around pH 4.75 .

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both A and R are false
46
MCQ (Single Correct Answer)

Assertion (A) The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid.

Reason (R) Hydrogen sulphide is a weak acid.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both $A$ and $R$ are false
47
MCQ (Single Correct Answer)

Assertion (A) For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property.

Reason (R) Equilibrium constant is independent of temperature.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both $A$ and $R$ are false
48
MCQ (Single Correct Answer)

Assertion (A) Aqueous solution of ammonium carbonate is basic.

Reason (R) Acidic/basic nature of a salt solution of a salt of weak acid and weak base depends on $\mathrm{K}_{\mathrm{a}}$ and $\mathrm{K}_{\mathrm{b}}$ value of the acid and the base forming it.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both $A$ and $R$ are false
49
MCQ (Single Correct Answer)

Assertion (A) An aqueous solution of ammonium acetate can act as a buffer.

Reason (R) Acetic acid is a weak acid and $\mathrm{NH}_4 \mathrm{OH}$ is a weak base.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both A and R are true but R is not the correct explanation of A
C
$A$ is false but $R$ is true
D
Both $A$ and $R$ are false