Assertion (A) Hofmann's bromamide reaction is given by primary amines.
Reason (R) Primary amines one more basic than secondary amines.
Assertion (A) N-ethylbenzene sulphonamide is soluble in alkali.
Reason (R) Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
Assertion (A) N, N-diethylbenzene sulphonamide is insoluble in alkali.
Reason (R) Sulphonyl group attached to nitrogen atom is strong electron withdrawing group.
Assertion (A) Only a small amount of HCl is required in the reduction of nitro compounds with iron scrap and HCl in the presence of steam.
Reason (R) $\mathrm{FeCl}_2$ formed gets hydrolysed to release HCl during the reaction.
Assertion (A) Aromatic $1^{\circ}$ amines can be prepared by Gabriel phthalimide synthesis.
Reason (R) Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.