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31
Subjective

but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.

Explanation

Nature of chemical reaction occurring on $>\mathrm{C}=\mathrm{C}<$ bond or $>\mathrm{C}=\mathrm{O}$ bond can be explained on the basis of nature of bond between $>\mathrm{C}=\mathrm{C}<$ and $>\mathrm{C}=\mathrm{O}$.

Thus, in $>\mathrm{C}=\mathrm{O}$ carbon acquires partially positive charge and O acquires partially negative charge and show nucleophilic addition reaction to the electrophilic carbonyl carbon. On the other hand, $>\mathrm{C}=\mathrm{C}<$ undergo electrophilic addition reaction due to nucleophilic nature of $>\mathrm{C}=\mathrm{C}<$ which contains $\pi$ bond.

32
Subjective

Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?

Explanation

Carboxylic acid contain carbonyl group but do not show nucleophilic addition reaction like aldehyde and ketone. Due to resonance as shown below the partial positive charge on carbonyl carbon atom is reduced.

33
Subjective

Identify the compounds A, B and C in the following reaction.

$\mathrm{CH}_3-\mathrm{Br} \xrightarrow{\text { Mg/ether }}[A] \xrightarrow[\text { (i) Water }]{\text { (i) } \mathrm{CO}_2}[B] \xrightarrow[\Delta]{\mathrm{CH}_3 \mathrm{OH} / \mathrm{H}^{+}}[C]$

Explanation

Complete chemical conversion can be done as

34
Subjective

Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom ( $-0-\mathrm{H}$ )?

Explanation

Carboxylic acids are more acidic than alcohol or phenol, although all of them have $\mathrm{O}-\mathrm{H}$ bond. This can be explained on the basis of stability of conjugate base obtained after removal of $\mathrm{H}^{+}$from acid or phenol.

Hence, dissociation of $\mathrm{O}-\mathrm{H}$ bond in case of carboxylic acid become easier than that of phenol. Hence, carboxylic acid are stronger acid than phenol.

35
Subjective

Complete the following reaction sequence.

Explanation

The complete chemical transformation can be shown as