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21
MCQ (Multiple Correct Answer)

Which of the following are benzylic alcohols?

A
$\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{OH}$
B
$\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2 \mathrm{OH}$
C
D
22
Subjective

What is the structure and IUPAC name of glycerol?

Explanation

Glycerol is the trihydric alcohol. Structure of glycerol is

So, IUPAC name is $-$ propoan- 1, 2, 3-triol.

23
Subjective

Write the IUPAC name of the following compounds.

Explanation

The correct IUPAC name of the following compounds are given below

(a)

IUPAC name $\to$ 3-ethyl-5-methylhexan-2, 4-diol.

IUPAC name $\rightarrow$ 1-methoxy-3-nitrocyclohexane.

24
Subjective

Write the IUPAC name of the compound given below.

Explanation

The IUPAC name of the compound given below is

3-methylpent-2-ene-1, 2-diol.

25
Subjective

Name the factors responsible for the solubility of alcohols in water.

Explanation

Solubility of alcohols in water depends upon the two factors.

(i) Hydrogen bonding Higher the extent of hydrogen bonding, higher is the solubility. The hydrogen group of alcohol form hydrogen bonding. Solubility increases with increase in the number of - OH groups in alcohols of comparable molecular masses.

(I) Compound (II) will form stronger H -bond due to two - OH group and hence has higher boiling point.

(ii) Size of alkyl/aryl group Higher the size of alkyl/aryl group (hydrocarbon part), lower is the extent of hydrogen bonding and lower is the solubility. Hence,

$$\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{OH}>\mathrm{CH}_3 \mathrm{CH}_2-\mathrm{CH}_2 \mathrm{OH}>\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2-\mathrm{CH}_2 \mathrm{OH}$$