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41
Subjective

Explain why is OH group in phenols more strongly held as compared to OH group in alcohols?

Explanation

In phenols, the electron pairs on oxygen atom of -OH group are in conjugation (or resonance) with $\pi$ electrons of the ring and the following resonating structures are possible

Out of these five resonating structures, II, III and IV structures contain a carbon-oxygen double bond character. In other words, carbon-oxygen bond in phenol acquires a partial double bond character due to resonance. But in alcohols carbon-oxygen bond in alcohols is purely single bond. Therefore, -OH group in phenols is more strongly held as compared to - OH group in alcohols.

42
Subjective

Explain why nucleophilic substitution reactions are not very common in phenols?

Explanation

Resonance is an important factor in phenols. During resonance -OH group in phenol gives its electrons to the benzene ring. As a result of this, the electron density on benzene ring is very high. This increased electron density repels nucleophiles.

Therefore, nucleophiles cannot attack the benzene ring and phenols usually do not give nucleophilic substitution reaction.

43
Subjective

Preparation of alcohols from alkenes involves the electrophilic attack on alkene carbon atom. Explain its mechanism.

Explanation

Preparation of alcohols from alkene by the hydration of alkenes in presence of sulphuric acid.

$$\mathrm{CH}_2=\mathrm{CH}_2+\mathrm{H}_2 \mathrm{O} \xrightarrow{\mathrm{H}^{+}} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}$$

This addition reaction takes place in accordance with Markownikoff's rule.

Mechanism The mechanism of the reaction involves the following three steps

Step 1 Protonation of alkene to form carbocation by electrophilic attack of $\mathrm{H}_3^{+} \mathrm{O}$.

Step 2 Attack of water molecule to the secondary carbocation.

Step 3 Loss of the hydrogen from the protonated alcohol.

44
Subjective

Explain why is $O=\mathrm{C}=O$ non-polar while $\mathrm{R}-O-\mathrm{R}$ is polar?

Explanation

$\mathrm{CO}_2$ is a linear molecule. The dipole moment of two $\mathrm{C}=\mathrm{O}$ bonds are equal and opposite and they cancel each other and hence the dipole moment of $\mathrm{CO}_2$ is zero and it is a non-polar molecule.

While for ethers, two dipoles are pointing in the same direction. These two dipoles do not cancel the effect of each other. Therefore, there is a finite resultant dipoles and hence $R-O-R$ is a polar molecule.

45
Subjective

Why is the reactivity of all the three classes of alcohols with conc. HCl and $\mathrm{ZnCl}_2$ (Lucas reagent) different?

Explanation

The reaction of alcohols with Lucas reagent (conc. HCl and $\mathrm{ZnCl}_2$ ) follow $\mathrm{S}_{\mathrm{N}}{ }^1$ mechanism. $\mathrm{S}_{\mathrm{N}}{ }^1$ mechanism depends upon the stability of carbocations (intermediate). More stable the intermediate carbocation, more reactive is the alcohol.

Tertiary carbocations are most stable among the three classes of carbocations and the order of the stability of carbocation is $3^{\circ}>2^{\circ}>1^{\circ}$. This order, inturn, reflects the order of reactivity of three classes of alcohols i.e., $3^{\circ}>2^{\circ}>1^{\circ}$.

Thus, as the stability of carbocations are different so the reactivity of all the three classes of alcohols with Lucas reagent is different.