Assertion (A) p-nitrophenol is more acidic than phenol.
Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
Assertion (A) IUPAC name of the compound
is 2-ethoxy-2-methylethane
Reason (R) In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by - OR or - OAr group [where, $\mathrm{R}=$ alkyl group and $\mathrm{Ar}=$ aryl group].
Assertion (A) Bond angle in ethers is slightly less than the tetrahedral angle.
Reason (R) There is a repulsion between the two bulky $(-R)$ groups.
Assertion (A) Boiling points of alcohols and ethers are high.
Reason (R) They can form intermolecular hydrogen-bonding.
Assertion (A) Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.
Reason (R) Lewis acid polarises the bromine molecule.