Match the elements given in Column I with the properties mentioned in Column II.
Column I | Column II | ||
---|---|---|---|
A. | Li | 1. | Insoluble sulphate |
B. | Na | 2. | Strongest monoacidic base |
C. | Ca | 3. | Most negative $E^{\ominus}$ value among alkali metals |
D. | Ba | 4. | Insoluble oxalate |
5. | 6s$$^2$$ outer electronic configuration |
A. $\rightarrow(3)$
B. $\rightarrow(2)$
C. $\rightarrow(4)$
D. $\rightarrow(5)$
A. Li-Most negative $E^{-}$among alkali metals
[Due to very high hydration energy the resulting $E^{\ominus}$ is most negative].
B. Na-Strongest monoacidic base
[Alkalies are more acidic than alkaline earth metals. LiOH has covalent character].
C. Ca-insoluble oxalate
[Calciuim oxalate is insoluble in water]
D. Ba-Insoluble sulphate
[Hydration energy decreases as size of cation increases].
$6 s^2$ outer electronic configuration
$$\left.{ }_{56} \mathrm{Ba}=1 s^2, 2 s^2, 2 p^6, 3 s^2, 3 p^6, 3 d^{10}, 4 s^2, 4 p^6, 4 d^{10}, 5 s^2, 5 p^6, 6 s^2\right]$$
Match the compounds given in Column I with their uses mentioned in Column II.
Column I | Column II | ||
---|---|---|---|
A. | CaCO$$_3$$ | 1. | Dentistry, ornamental work |
B. | Ca(OH)$$_2$$ | 2. | Manufacture of sodium carbonate from caustic soda |
C. | CaO | 3. | Manufacture of high quality paper |
D. | CaSO$$_4$$ | 4. | Used in white washing |
A. $\rightarrow$ (3)
B. $\rightarrow$ (4)
C. $\rightarrow(2)$
D. $\rightarrow 1$
A. $\mathrm{CaCO}_3-$ Manufacture of high quality paper
B. $\mathrm{Ca}(\mathrm{OH})_2-$ Used in white washing
C. $\mathrm{CaO}-$ Manufacture of sodium carbonate from caustic soda
D. $\mathrm{CaSO}_4-$ Dentistry, ornamental work
Match the elements given in Column I with the colour they impart to the flame given in Column II.
Column I | Column II | ||
---|---|---|---|
A. | Cs | 1. | Apple green |
B. | Na | 2. | Violet |
C. | K | 3. | Brick reduction |
D. | Ca | 4. | Yellow |
E. | Sr | 5. | Crimson red |
F. | Ba | 6. | Blue |
A. $\rightarrow$ (6)
B. $\rightarrow$ (4)
C. $\rightarrow(2)$
D. $\rightarrow$ (3)
E. $\rightarrow$ (5)
F. $\rightarrow 1$
Elements with the characteristic flame colour are as follows
A. Cs - Blue
B. $\mathrm{Na}-$ Yellow
C. K - Violet
D. Ca - Brick red
E. Sr - Crimson red
F. Ba - Apple green
Flame colours are produced from the movement of the electrons in the metal ions present in the compounds. These movement of electrons (electronic excitation-de-excitation) requires energy.
Each atom has particular energy gap between ground and excited energy level therefore each of these movements involves a specific amount of energy emitted as light energy, and each corresponds to a particular colour. As we know energy gap between ground and excited state energy level increases wavelength of decreases and complemently colouer is observed as a result.
Assertion (A) The carbonate of lithium decomposes easily on heating to form lithium oxide and $\mathrm{CO}_2$.
Reason (R) Lithium being very small in size polarises large carbonate ion leading to the formation of more stable $\mathrm{Li}_2 \mathrm{O}$ and $\mathrm{CO}_2$.
Assertion (A) Beryllium carbonate is kept in the atmosphere of carbon dioxide.
Reason (R) Beryllium carbonate is unstable and decomposes to give beryllium oxide and carbon dioxide.