50 What is the importance of heavy water?
Following are the importance of heavy water
(i) It is extensively used as a moderator in nuclear reactors.
(ii) It is used as a tracer compound in the study of reaction mechanism.
(iii) It is used for the preparation of other deuterium compounds such as $\mathrm{CD}_4, \mathrm{D}_2 \mathrm{SO}_4$, etc.
Write the Lewis structure of hydrogen peroxide.
The Lewis structure of hydrogen peroxide is
An acidic solution of hydrogen peroxide behaves as an oxidising as well as reducing agent. Illustrate it with the help of a chemical equation.
Following are the chemical equation of $\mathrm{H}_2 \mathrm{O}_2$ in which it behaves as an oxidising as well as reducing agent
(i) $\mathrm{H}_2 \mathrm{O}_2$ oxidises acidified KI to iodine.
$$2 \mathrm{KI}+\mathrm{H}_2 \mathrm{O}_2+\mathrm{H}_2 \mathrm{SO}_4 \longrightarrow \mathrm{I}_2+\mathrm{K}_2 \mathrm{SO}_4+2 \mathrm{H}_2 \mathrm{O}$$
(ii) $\mathrm{H}_2 \mathrm{O}_2$ reduces $\mathrm{KMnO}_4$ to $\mathrm{MnO}_2$ in alkaline medium.
$$2 \mathrm{KMnO}_4+3 \mathrm{H}_2 \mathrm{O}_2 \longrightarrow 2 \mathrm{MnO}_2+2 \mathrm{KOH}+3 \mathrm{O}_2+2 \mathrm{H}_2 \mathrm{O}$$
With the help of suitable examples, explain the property of $\mathrm{H}_2 \mathrm{O}_2$ that is responsible for its bleaching action?
The bleaching action of hydrogen peroxide is due to the nascent oxygen which it liberates on decomposition.
$$\mathrm{H}_2 \mathrm{O}_2 \longrightarrow \mathrm{H}_2 \mathrm{O}+[\mathrm{O}]$$
The nascent oxygen combines with colouring matter, in turn, gets oxidised. Thus, the bleaching action of $\mathrm{H}_2 \mathrm{O}_2$ is due to the oxidation of colouring matter by nascent oxygen. It is used for the bleaching of delicate materials like ivory, feathers, silk, wool etc.
Colouring matter $+[\mathrm{O}] \longrightarrow$ Colourless matter
Why is water molecule polar?
Oxygen is more electronegative $(\mathrm{EN}=3.5)$ than hydrogen $(\mathrm{EN}=2.1)$ hence, $\mathrm{O}-\mathrm{H}$ bond is polar. In the water molecule, two polar $\mathrm{O}-\mathrm{H}$ bonds are present which are held together at an angle of $104.5^{\circ}$. Due to the resultant of these two dipoles, water molecule is polar and has an dipole moment of 1.84 Debye.