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50
Subjective

50 What is the importance of heavy water?

Explanation

Following are the importance of heavy water

(i) It is extensively used as a moderator in nuclear reactors.

(ii) It is used as a tracer compound in the study of reaction mechanism.

(iii) It is used for the preparation of other deuterium compounds such as $\mathrm{CD}_4, \mathrm{D}_2 \mathrm{SO}_4$, etc.

51
Subjective

Write the Lewis structure of hydrogen peroxide.

Explanation

The Lewis structure of hydrogen peroxide is

52
Subjective

An acidic solution of hydrogen peroxide behaves as an oxidising as well as reducing agent. Illustrate it with the help of a chemical equation.

Explanation

Following are the chemical equation of $\mathrm{H}_2 \mathrm{O}_2$ in which it behaves as an oxidising as well as reducing agent

(i) $\mathrm{H}_2 \mathrm{O}_2$ oxidises acidified KI to iodine.

$$2 \mathrm{KI}+\mathrm{H}_2 \mathrm{O}_2+\mathrm{H}_2 \mathrm{SO}_4 \longrightarrow \mathrm{I}_2+\mathrm{K}_2 \mathrm{SO}_4+2 \mathrm{H}_2 \mathrm{O}$$

(ii) $\mathrm{H}_2 \mathrm{O}_2$ reduces $\mathrm{KMnO}_4$ to $\mathrm{MnO}_2$ in alkaline medium.

$$2 \mathrm{KMnO}_4+3 \mathrm{H}_2 \mathrm{O}_2 \longrightarrow 2 \mathrm{MnO}_2+2 \mathrm{KOH}+3 \mathrm{O}_2+2 \mathrm{H}_2 \mathrm{O}$$

53
Subjective

With the help of suitable examples, explain the property of $\mathrm{H}_2 \mathrm{O}_2$ that is responsible for its bleaching action?

Explanation

The bleaching action of hydrogen peroxide is due to the nascent oxygen which it liberates on decomposition.

$$\mathrm{H}_2 \mathrm{O}_2 \longrightarrow \mathrm{H}_2 \mathrm{O}+[\mathrm{O}]$$

The nascent oxygen combines with colouring matter, in turn, gets oxidised. Thus, the bleaching action of $\mathrm{H}_2 \mathrm{O}_2$ is due to the oxidation of colouring matter by nascent oxygen. It is used for the bleaching of delicate materials like ivory, feathers, silk, wool etc.

Colouring matter $+[\mathrm{O}] \longrightarrow$ Colourless matter

54
Subjective

Why is water molecule polar?

Explanation

Oxygen is more electronegative $(\mathrm{EN}=3.5)$ than hydrogen $(\mathrm{EN}=2.1)$ hence, $\mathrm{O}-\mathrm{H}$ bond is polar. In the water molecule, two polar $\mathrm{O}-\mathrm{H}$ bonds are present which are held together at an angle of $104.5^{\circ}$. Due to the resultant of these two dipoles, water molecule is polar and has an dipole moment of 1.84 Debye.