ExamGOAL
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45
Subjective

Match the following.

Column I Column II
A. X-rays 1. $$v=10^0-10^4$$ Hz
B. Ultraviolet wave (UV) 2. $$v=10^{10}$$ Hz
C. Long radio waves 3. $$v=10^{16}$$ Hz
D. Microwave 4. $$v=10^{18}$$ Hz

Explanation

A. $\rightarrow(4)$

B. $\rightarrow(3)$

C. $\rightarrow$ (1)

D. $\rightarrow(2)$

Name Frequency Uses
A. X-rays $$
2 \times 10^{16}-3 \times 10^{19} \mathrm{~Hz}
$$
Medical pictures, material testing
B. Ultraviolet wave (UV) $$
7.9 \times 10^{14}-2 \times 10^{16} \mathrm{~Hz}
$$
Germisidal lamp
C. Long radio waves $$
10^0-10^4 \mathrm{~Hz}
$$
Signal transmission
D. Microwave $$
1 \times 10^9-5 \times 10^{11} \mathrm{~Hz}
$$
Cooking radar

46
Subjective

Match the following.

Column I Column II
A. Photon 1. Value is 4 for N-shell
B. Electron 2. Probability density
C. $${\psi ^2}$$ 3. Always positive value
D. Principle quantum number n 4. Exhibits both momentum and wavelength

Explanation

A. $\rightarrow(4)$

B. $\rightarrow$ (4)

C. $\rightarrow(2,3)$

D. $\rightarrow(1,3)$

A. Photon has particle nature as well as wave nature. It exhibits both momentum and wavelength.

B. Electron also has particle nature as well as wave nature. Thus, it also exhibits both momentum and wavelength.

C. $\psi^2$ represents probability density of electron and always has positive values.

D. Principal quantum number $n=4$ for $N$-shell.

$$\begin{array}{rrrr} & \mathrm{K} &\mathrm{L} & \mathrm{M} & \mathrm{N} \\ & n=\quad 1 & 2 & 3 & 4 \end{array}$$

It always has positive values.

47
Subjective

Match species given in Column I with the electronic configuration given in Column II.

Column Column II
A. Cr 1. $$
[\operatorname{Ar}] 3 d^8 4 s^0
$$
B. Fe$$^{2+}$$ 2. $$
[\operatorname{Ar}] 3 d^{10} 4 s^1
$$
C. Ni$$^{2+}$$ 3. $$
[\operatorname{Ar}] 3 d^6 4 s^0
$$
D. Cu 4. $$
[\operatorname{Ar}] 3 d^5 4 s^1
$$
5. $$
[\operatorname{Ar}] 3 d^6 4 s^2
$$

Explanation

A. $\rightarrow(4)$

B. $\rightarrow$ (3)

C. $\rightarrow(1)$

D. $\rightarrow(2)$

A. $\operatorname{Cr}(Z=24)=1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 3 d^5 4 s^1=[\operatorname{Ar}] 3 d^5 4 s^1$

B. $\mathrm{Fe}^{2+}(Z=26)=1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 3 d^6 4 s^0=[\operatorname{Ar}] 3 d^6 4 s^0$

C. $\mathrm{Ni}^{2+}(Z=28)=1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 3 d^8 4 s^0=[\mathrm{Ar}] 3 d^8 4 s^0$

D. $\mathrm{Cu}(Z=29)=1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 3 d^{10} 4 s^1=[\mathrm{Ar}] 3 d^{10} 4 s^1$

48
MCQ (Single Correct Answer)

Assertion (A) All isotopes of a given element show the same type of chemical behaviour.

Reason (R) The chemical properties of an atom are controlled by the number of electrons in the atom.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both $A$ and $R$ are false
49
MCQ (Single Correct Answer)

Assertion (A) Black body is an ideal body that emits and absorbs radiations of all frequencies.

Reason (R) The frequency of radiation emitted by a body goes from a lower frequency to higher frequency with an increase in temperature.

A
Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
B
Both $A$ and $R$ are true but $R$ is not the correct explanation of $A$
C
$A$ is true but $R$ is false
D
Both $A$ and $R$ are false