Assertion (A) Increasing order or acidity of hydrogen halides is $\mathrm{HF}<\mathrm{HCI}<\mathrm{HBr}<\mathrm{HI}$.
Reason (R) While comparing acids formed by the elements belonging to the same group of periodic table, H-A bond strength is a more important factor in determining acidity of an acid than the polar nature of the bond.
Assertion (A) A solution containing a mixture of acetic acid and sodium acetate maintains a constant value of pH on addition of small amounts of acid or alkali.
Reason (R) A solution containing a mixture of acetic acid and sodium acetate acts as buffer solution around pH 4.75 .
Assertion (A) The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid.
Reason (R) Hydrogen sulphide is a weak acid.
Assertion (A) For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property.
Reason (R) Equilibrium constant is independent of temperature.
Assertion (A) Aqueous solution of ammonium carbonate is basic.
Reason (R) Acidic/basic nature of a salt solution of a salt of weak acid and weak base depends on $\mathrm{K}_{\mathrm{a}}$ and $\mathrm{K}_{\mathrm{b}}$ value of the acid and the base forming it.