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17
MCQ (Single Correct Answer)

What will be the correct order of vapour pressure of water, acetone and ether at $30^{\circ} \mathrm{C}$ ? Given that among these compounds, water has maximum boiling point and ether has minimum boiling point?

A
Water < ether < acetone
B
Water < acetone < ether
C
Ether < acetone < water
D
Acetone < ether < water
18
MCQ (Single Correct Answer)

At 500 K , equilibrium constant, $\mathrm{K}_{\mathrm{c}}$, for the following reaction is 5.

$$\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{I}_2(\mathrm{~g}) \rightleftharpoons \mathrm{HI}(\mathrm{g})$$

What would be the equilibrium constant $\mathrm{K}_{\mathrm{c}}$ for the reaction?

$$2 \mathrm{HI}(\mathrm{g}) \rightleftharpoons \mathrm{H}_2(\mathrm{~g})+\mathrm{I}_2(\mathrm{~g})$$

A
0.04
B
0.4
C
25
D
2.5
19
MCQ (Single Correct Answer)

In which of the following reactions, the equilibrium remains unaffected on addition of small amount of argon at constant volume?

A
$\mathrm{H}_2(\mathrm{g})+\mathrm{I}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{HI}(\mathrm{g})$
B
$\mathrm{PCl}_5(\mathrm{g}) \rightleftharpoons \mathrm{PCl}_3(\mathrm{g})+\mathrm{Cl}_2(\mathrm{g})$
C
$\mathrm{N}_2(\mathrm{g})+3 \mathrm{H}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{g})$
D
The equilibrium will remain unaffected in all the three cases
20
MCQ (Multiple Correct Answer)

For the reaction $\mathrm{N}_2 \mathrm{O}_4(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}_2(\mathrm{~g})$, the value of K is 50 at 400 K and 1700 at 500 K . Which of the following option(s) is/are correct?

A
The reaction is endothermic
B
The reaction is exothermic
C
If $\mathrm{NO}_2(g)$ and $\mathrm{N}_2 \mathrm{O}_4(\mathrm{~g})$ are mixed at 400 K at partial pressures 20 bar and 2 bar respectively, more $\mathrm{N}_2 \mathrm{O}_4(\mathrm{~g})$ will be formed
D
The entropy of the system increases
21
MCQ (Multiple Correct Answer)

At a particular temperature and atmospheric pressure, the solid and liquid phases of a pure substance can exist in equilibrium. Which of the following term defines this temperature?

A
Normal melting point
B
Equilibrium temperature
C
Boiling point
D
Freezing point