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15
MCQ (Single Correct Answer)

Which of the following options will be correct for the stage of half completion of the reaction $\mathrm{A} \rightleftharpoons \mathrm{B}$ ?

A
$\Delta G^{\ominus}=0$
B
$\Delta G^{\ominus}>0$
C
$\Delta \mathrm{G}^{\ominus}<0$
D
$\Delta G^{\ominus}=-R T \ln K$
16
MCQ (Single Correct Answer)

On increasing the pressure, in which direction will the gas phase reaction proceed to re-establish equilibrium, is predicted by applying the Le-Chatelier's principle. Consider the reaction,

$$\mathrm{N}_2(\mathrm{~g})+3 \mathrm{H}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{~g})$$

Which of the following is correct, if the total pressure at which the equilibrium is established, is increased without changing the temperature?

A
$K$ will remain same
B
$K$ will decrease
C
$K$ will increase
D
$K$ will increase initially and decrease when pressure is very high
17
MCQ (Single Correct Answer)

What will be the correct order of vapour pressure of water, acetone and ether at $30^{\circ} \mathrm{C}$ ? Given that among these compounds, water has maximum boiling point and ether has minimum boiling point?

A
Water < ether < acetone
B
Water < acetone < ether
C
Ether < acetone < water
D
Acetone < ether < water
18
MCQ (Single Correct Answer)

At 500 K , equilibrium constant, $\mathrm{K}_{\mathrm{c}}$, for the following reaction is 5.

$$\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{I}_2(\mathrm{~g}) \rightleftharpoons \mathrm{HI}(\mathrm{g})$$

What would be the equilibrium constant $\mathrm{K}_{\mathrm{c}}$ for the reaction?

$$2 \mathrm{HI}(\mathrm{g}) \rightleftharpoons \mathrm{H}_2(\mathrm{~g})+\mathrm{I}_2(\mathrm{~g})$$

A
0.04
B
0.4
C
25
D
2.5
19
MCQ (Single Correct Answer)

In which of the following reactions, the equilibrium remains unaffected on addition of small amount of argon at constant volume?

A
$\mathrm{H}_2(\mathrm{g})+\mathrm{I}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{HI}(\mathrm{g})$
B
$\mathrm{PCl}_5(\mathrm{g}) \rightleftharpoons \mathrm{PCl}_3(\mathrm{g})+\mathrm{Cl}_2(\mathrm{g})$
C
$\mathrm{N}_2(\mathrm{g})+3 \mathrm{H}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{g})$
D
The equilibrium will remain unaffected in all the three cases