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14
MCQ (Single Correct Answer)

$\mathrm{K}_{\mathrm{a}}$ for $\mathrm{CH}_3 \mathrm{COOH}$ is $1.8 \times 10^{-5}$ and $\mathrm{K}_{\mathrm{b}}$ for $\mathrm{NH}_4 \mathrm{OH}$ is $1.8 \times 10^{-5}$. The pH of ammonium acetate will be

A
7.005
B
4.75
C
7.0
D
Between 6 and 7
15
MCQ (Single Correct Answer)

Which of the following options will be correct for the stage of half completion of the reaction $\mathrm{A} \rightleftharpoons \mathrm{B}$ ?

A
$\Delta G^{\ominus}=0$
B
$\Delta G^{\ominus}>0$
C
$\Delta \mathrm{G}^{\ominus}<0$
D
$\Delta G^{\ominus}=-R T \ln K$
16
MCQ (Single Correct Answer)

On increasing the pressure, in which direction will the gas phase reaction proceed to re-establish equilibrium, is predicted by applying the Le-Chatelier's principle. Consider the reaction,

$$\mathrm{N}_2(\mathrm{~g})+3 \mathrm{H}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{~g})$$

Which of the following is correct, if the total pressure at which the equilibrium is established, is increased without changing the temperature?

A
$K$ will remain same
B
$K$ will decrease
C
$K$ will increase
D
$K$ will increase initially and decrease when pressure is very high
17
MCQ (Single Correct Answer)

What will be the correct order of vapour pressure of water, acetone and ether at $30^{\circ} \mathrm{C}$ ? Given that among these compounds, water has maximum boiling point and ether has minimum boiling point?

A
Water < ether < acetone
B
Water < acetone < ether
C
Ether < acetone < water
D
Acetone < ether < water
18
MCQ (Single Correct Answer)

At 500 K , equilibrium constant, $\mathrm{K}_{\mathrm{c}}$, for the following reaction is 5.

$$\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{I}_2(\mathrm{~g}) \rightleftharpoons \mathrm{HI}(\mathrm{g})$$

What would be the equilibrium constant $\mathrm{K}_{\mathrm{c}}$ for the reaction?

$$2 \mathrm{HI}(\mathrm{g}) \rightleftharpoons \mathrm{H}_2(\mathrm{~g})+\mathrm{I}_2(\mathrm{~g})$$

A
0.04
B
0.4
C
25
D
2.5