Match the species in Column I with the geometry/shape in Column II.
Column I | Column II | ||
---|---|---|---|
A. | $$ \mathrm{H}_3 \mathrm{O}^{+} $$ |
1. | Linear |
B. | $$ \mathrm{HC} \equiv \mathrm{CH} $$ |
2. | Angular |
C. | $$ \mathrm{ClO}_2^{-} $$ |
3. | Tetrahedral |
D. | NH$$_4^+$$ | 4. | Trigonal bipyramidal |
5. | Pyramidal |
A. $\rightarrow(5)$
B. $\rightarrow$ (1)
C. $\rightarrow(2)$
$\mathrm{D} \rightarrow(3)$
A. $\mathrm{H}_3 \mathrm{O}^{+}=3 b p+1 / p$ pyramidal shape
B. $\mathrm{HC} \equiv \mathrm{CH} \Rightarrow$ linear as sphybridised shape
C. $\mathrm{ClO}_2^{-}=2 b p+2 / p \Rightarrow$ angular shape
D. $\mathrm{NH}_4^{+}=4 b p+0 / p \Rightarrow$ tetrahedral shape
Match the species in Column I with the bond order in Column II.
Column I | Column II | ||
---|---|---|---|
A. | NO | 1. | 1.5 |
B. | CO | 2. | 2.0 |
C. | O$$_2^-$$ | 3. | 2.5 |
D. | O$$_2$$ | 4. | 3.0 |
A. $\rightarrow$ (3)
B. $\rightarrow$ (4)
C. $\rightarrow(1)$
D. $\rightarrow(2)$
$$ \begin{gathered} \text { A. } N O(7+8=15)=\sigma 1 s^2, \sigma^{\star} 1 s^2, \sigma 2 s^2, \sigma^{\star} 2 s^2, \sigma 2 p_z^2, \pi 2 p_x^2 \approx \pi 2 p_y^2, \pi \star 2 p_x^1 \\ \text { Bond order }=\frac{1}{2}\left(N_b-N_a\right)=\frac{10-5}{2}=2.5 \end{gathered}$$
B. $\mathrm{CO}(6+8=14)=\sigma 1 s^2, \sigma^{\star} 1 s^2, \sigma 2 s^2, \sigma^{\star} 2 s^2, \sigma 2 p_z^2, \pi 2 p_x^2 \approx \pi 2 p_y^2$
Bond order $=\frac{10-4}{2}=3$
C. $\mathrm{O}_2^{-}(8+8+1=17)=\sigma 1 s^2, \sigma^{\star} 1 s^2, \sigma 2 s^2, \sigma * 2 s^2, \sigma 2 p_z^2, \pi 2 p_x^2 \approx \pi 2 p_y^2, \pi * 2 p_x^2 \approx \pi * 2 p_y^1$
Bond order $=\frac{10-7}{2}=1.5$
D. $\mathrm{O}_2(8+8=16)=\sigma 1 s^2, \sigma^{\star} 1 s^2, \sigma 2 s^2, \sigma^{\star} 2 s^2, \sigma 2 p_z^2, \pi 2 p_x^2 \approx \pi 2 p_y^2, \pi^{\star} 2 p_x^1 \approx \pi^{\star} 2 p_y^1$
Bond order $=\frac{10-6}{2}=2$
Match the items given in Column I with examples given in Column II.
Column I | Column II | ||
---|---|---|---|
A. | Hydrogen bond | 1. | C |
B. | Resonance | 2. | LiF |
C. | Ionic solid | 3. | H$$_2$$ |
D. | Covalent solid | 4. | HF |
5. | O$$_3$$ |
A. $\rightarrow$ (4)
B. $\rightarrow$ (5)
C. $\rightarrow$ (2)
D. $\rightarrow$ (1)
A. Hydrogen bond $\rightarrow \mathrm{HF}$
B. Resonance $\rightarrow \mathrm{O}_3$
C. Ionic bond $\rightarrow$ LiF
D. Covalent solid $\rightarrow \mathrm{C}$
Match the shape of molecules in Column I with the type of hybridisation in Column II.
Column I | Column II | ||
---|---|---|---|
A. | Tetrahedral | 1. | sp$$^2$$ |
B. | Trigonal | 2. | sp |
D. | Linear | 4. | sp$$^3$$ |
A. $\rightarrow(3)$
B. $\rightarrow(1)$
C. $\rightarrow(2)$
A. Tetrahedral shape $-s p^3$ hybridisation
B. Trigonal shape $-s p^2$ hybridisation
C. Linear shape - sp hybridisation
Assertion (A) Sodium chloride formed by the action of chlorine gas on sodium metal is a stable compound.
Reason (R) This is because sodium and chloride ions acquire octet in sodium chloride formation.