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3
MCQ (Single Correct Answer)

The types of hybrid orbitals of nitrogen in $\mathrm{NO}_2^{+}, \mathrm{NO}_3^{-}$and $\mathrm{NH}_4^{+}$ respectively are expected to be

A
$s p, s p^3$ and $s p^2$
B
$s p, s p^2$ and $s p^3$
C
$s p^2, s p$ and $s p^3$
D
$s p^2, s p^3$ and $s p$
4
MCQ (Single Correct Answer)

Hydrogen bonds are formed in many compounds e.g., $\mathrm{H}_2 \mathrm{O}, \mathrm{HF}, \mathrm{NH}_3$. The boiling point of such compounds depends to a extent on the strength of hydrogen bond and the number of hydrogen bonds. The correct decreasing order of the boiling points above compounds is

A
$\mathrm{HF}>\mathrm{H}_2 \mathrm{O}>\mathrm{NH}_3$
B
$\mathrm{H}_2 \mathrm{O}>\mathrm{HF}>\mathrm{NH}_3$
C
$\mathrm{NH}_3>\mathrm{HF}>\mathrm{H}_2 \mathrm{O}$
D
$\mathrm{NH}_3>\mathrm{H}_2 \mathrm{O}>\mathrm{HF}$
5
MCQ (Single Correct Answer)

In $\mathrm{PO}_4^{3-}$ ion the formal charge on the oxygen atom of $\mathrm{P}-0$ bond is

A
+1
B
$$-$$1
C
$$-$$0.75
D
+0.75
6
MCQ (Single Correct Answer)

In $\mathrm{NO}_3^{-}$ion, the number of bond pairs and lone pairs of electrons on nitrogen atom are

A
2, 2
B
3, 1
C
1, 3
D
4, 0
7
MCQ (Single Correct Answer)

Which of the following species has tetrahedral geometry?

A
$\mathrm{BH}_4^{-}$
B
$\mathrm{NH}_2^{-}$
C
$\mathrm{CO}_3^{2-}$
D
$\mathrm{H}_3 \mathrm{O}^{+}$